Tag Archives: University of Rochester
For the first time, Rochester chemical engineers have demonstrated a ‘potassium-promoted’ catalyst’s potential for use on an industrial scale. Now, the Navy’s quest to power its ships by converting seawater into fuel is nearer fruition.
University of Rochester chemical engineers—in collaboration with researchers at the Naval Research Laboratory, the University of Pittsburgh, and OxEon Energy—have demonstrated that a potassium-promoted molybdenum carbide catalyst efficiently and reliably converts carbon dioxide to carbon monoxide, a critical step in turning seawater into fuel.
“This is the first demonstration that this type of molybdenum carbide catalyst can be used on an industrial scale,” says Marc Porosoff, assistant professor in the Department of Chemical Engineering at Rochester. In a paper in the journal Energy & Environmental Science, the researchers describe an exhaustive series of experiments they conducted at molecular, laboratory, and pilot scales to document the catalyst’s suitability for scale-up.
If navy ships could create their own fuel from the seawater they travel through, they could remain in continuous operation. Other than a few nuclear-powered aircraft carriers and submarines, most navy ships must periodically align themselves alongside tanker ships to replenish their fuel oil, which can be difficult in rough weather.
In 2014, a Naval Research Laboratory team led by Heather Willauer announced it had used a catalytic converter to extract carbon dioxide and hydrogen from seawater and then converted the gases into liquid hydrocarbons at a 92 percent efficiency rate.
Since then, the focus has been on increasing the efficiency of the process and scaling it up to produce fuel in sufficient quantities.
The carbon dioxide extracted from seawater is extremely difficult to convert directly into liquid hydrocarbons with existing methods. So, it is necessary to first convert carbon dioxide into carbon monoxide via the reverse water-gas shift (RWGS) reaction. The carbon monoxide can then be converted into liquid hydrocarbons via Fischer-Tropsch synthesis.
Typically, catalysts for RWGS contain expensive precious metals and deactivate rapidly under reaction conditions. However, the potassium-modified molybdenum carbide catalyst is synthesized from low-cost components and did not show any signs of deactivation during continuous operation of the 10-day pilot-scale study. That’s why this demonstration of the molybdenum carbide catalyst is important.
Amid the coronavirus pandemic, people in developed countries are assured of ample supplies of clean water to wash their hands as often as needed to protect themselves from the virus. And yet, nearly a third of the world’s population is not even assured of clean water for drinking. University of Rochester researchers have now found a way to address this problem by using sunlight—a resource that everyone can access—to evaporate and purify contaminated water with greater than 100 percent efficiency.
How is this possible? In a paper in Nature Sustainability, researchers in the laboratory of Chunlei Guo, professor of optics, demonstrate how a burst of femtosecond laser pulses etch the surface of a normal sheet of aluminum into a superwicking (water-attracting), super energy–absorbing material. Using sunlight to boil has long been recognized as a way to eliminate microbial pathogens and reduce deaths from diarrheal infections. But boiling water does not eliminate heavy metals and other contaminants. Experiments by the lab show that their new method reduces the presence of all common contaminants, such as detergent, dyes, urine, heavy metals, and glycerin, to safe levels for drinking.
Solar-based water purification can greatly reduce contaminants because nearly all the impurities are left behind when the evaporating water becomes gaseous and then condenses and gets collected. The most common method of solar-based water evaporation is volume heating, in which a large volume of water is heated but only the top layer can evaporate. This is obviously inefficient, Guo says, because only a small fraction of the heating energy gets used. A more efficient approach, called interfacial heating, places floating, multilayered absorbing and wicking materials on top of the water, so that only water near the surface needs to be heated. But the available materials all have to float horizontally on top of the water and cannot face the sun directly. Furthermore, the available wicking materials become quickly clogged with contaminants left behind after evaporation, requiring frequent replacement of the materials.
The panel developed by the Guo lab avoids these inefficiencies by pulling a thin layer of water out of the reservoir and directly onto the solar absorber surface for heating and evaporation. “Moreover, because we use an open-grooved surface, it is very easy to clean by simply spraying it,” Guo says.
“The biggest advantage,” he adds, “is that the angle of the panels can be continuously adjusted to directly face the sun as it rises and then moves across the sky before setting” —maximizing energy absorption. “There was simply nothing else resembling what we can do here,” Guo says.